Alexandru T. BALABANTexas A&M University at Galveston, SUAIon BOLOCANUniversitatea Petrol Gaze PloieºtiMiron Teodor CÃPROIUInstitutul de Chimie Organicã “C.D. Neniþescu” BucureºtiAndrei F. DÃNEÞUniversitatea BucureºtiCorneliu Mircea DAVIDESCUUniversitatea Politehnica TimiºoaraGheorghe DUCAAcademia de Stiinte a MoldoveiKamel EARARUniversitatea “Dunarea de Jos” GalatiLaurenþiu FILIPESCUUniversitatea Politehnica BucureºtiIonel HAIDUCAcademia RomânãValeriu V. JINESCUUniversitatea Politehnica BucureºtiJiri Jaromir KLEMESUniversity of Pannonia Veszprém UngariaJean-Marie LEHNUniversité Louis Pasteur, Strasbourg, FranþaTudor LUPASCUAcademia de Stiinte a MoldoveiAngela LUPUUniversitatea Politehnica BucureºtiIonel MANGALAGIUUniversitatea Alexandru Ioan Cuza Iasi

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Bucharest - RomaniaChem. Abs.: RCBUAU 67 (1) (1 - 204)

ISSN 0034-7752Vol. 67, no. 1, January, 2016

CONTENTS

F.H.Kamar, Aurelia Cristina Nechifor, Gh.Nechifor, M.H.Sallomi, A.D.JasemStudy of the Single and Binary Batch Systems to Remove Copper and Cadmium Ions from Aqueous Solutions usingDry Cabbage Leaves as Biosorbent Material...................................................................................................................................................1Mariana Deleanu, Gabriela M.Sanda, Camelia S.Stancu, Mona E.Popa, Anca V.SimaProfiles of Fatty Acids and the Main Lipid Peroxidation Products of Human Atherogenic Low Density Lipoproteins..........................8L.Tarko, Anca HirtopeanuQSAR Study Regarding the Inhibitory Activity of Some Iminosugars Against α-Glucosidase....................................................................13Laura-Ileana Socea, G.Saramet, C.Draghici, Stefania-Felicia Barbuceanu, Diana Carolina Ilies, B.SoceaResearch on the Synthesis and Characterization of New 1,3,4-oxadiazoles with 5H-dibenzo[a,d][7]annulene Moiety.....................17C.I.Tanase, F.Cocu, C.Draghici, M.T.Caproiu, Catalina Negut, Denisa Ioana UdeanuAcylated Prodrugs of PGF2α Analogues.........................................................................................................................................................20M.Ruse, Anca Angela Athanasiu, Loti Cornelia Oproiu, C.FilipescuStructure-color Correlation Study in the Class of Pre-formed Acid Azo Chromium (1:1) Complex Dyes Containingthe Sulfonic Group in the Diazotation Component.........................................................................................................................................26Georgeta Pavalache, V.Dorneanu, Antoanela PopescuA New HPLC Method for the Separation and Quantitative Determination of Loratadine.....................................................................30Alexandra Pica, A.FicaiA New Generation Antibacterial Film Forming Materials.............................................................................................................................34B.Tita, C.Morgovan, D.Tita, Teodora Alina NeagAnty-inflammatory Drugs Interacting with Zn(II) Metal Ion. Synthesis, characterization and thermal behaviour of thecomplex with ketoprofen...............................................................................................................................................................................38Gh.Romanescu, Mariana Iosub, I.Sandu, I.Minea, A.Enea, D.Dascalita, Oana-Elena HapciucSpatio-temporal Analysis of the Water Quality of the Ozana River................................................................................................................42G.A.Zainescu, Rodica Roxana Constantinescu, P.Voicu, Dana C.DeselnicuStudy on the Levigation Ability of Nutrients for Soils Treated with Titanium-containing Biopolymers...................................................48R.Guzman-Cabrera, J.R.Guzman-Sepulveda, A.Gonzales Parada, J.Rosales Garcia, M.Torres Cisneros, D.BaleanuDigital Processing of Thermographic Images for Medical Applications.......................................................................................................53D.Acatrinei, Carmen Gentimir(Amititeloaie), Catalina Zaharia(Avram), Cristina Oana Raducanu,Geanina Bogza, Liliana Chelaru, D.Vasincu, Otilia Boisteanu, M.CostuleanuRelationship of NR4A1 Agonists Biochemical Effects with Pre-B Lymphocytes Apoptosis.......................................................................57L.G.Bahrin, H.Hopf, P.G.Jones, K.Earar, L.M.BirsaSynthesis and Structural Characterization of a New Iodine-containing Phenacyl N,N-Diethylamino Carbodithioate............................61Lavinia Madalina Micu, D.I.Petanec, Maria Dumitrela Iosub-Ciur, S.Andrian, Ramona Amina PopoviciThe Heavy Metals Content in Leaves of the Forest Fruits (Hippophae rhamnoides and Rubus Fruticosus)from the Tailings Dumps Mining...................................................................................................................................................................64Roxana Popescu, Vlad C.Daliborca, Adinela Cimporescu, Cristina S.Vlad, Doina Verdes, Dorica Botau,Marioara N.Filimon, I.Pauliuc, C.Citu, V.DumitrascuChemical Properties and in vitro Antitumor Effects of Momordica Charantia Extracts in Different Solvents..........................................69Vasilica Popescu, Irina Crina Anca Sandu, G.PopescuColorimetric Evaluation of Chemical Modifications Generated by PAN Functionalization in Acid/Basc Mediumand Grafting with Chitosan............................................................................................................................................................................74M.F.Berceanu, Iulia Pinzaru, T.Bratu, Z.Crainiceanu, Lavinia Ceuta, F.Borcan, Dorina Coricovac, C.CituEvolution of Murine Melanoma in C57BL/6J Female Mice.A non-invasive evaluation..............................................................................81Lenuta-Maria Suta, Gabriela Vlase, T.Vlase, Germaine Savoiu-Balint, T.Olariu, Ionela Belu, Adriana Ledeti,M.-S.Murariu, Lavinia Stelea, I. LedetiThermal Characterization of Cholesterol in Air vs.Nitrogen Atmosphere.....................................................................................................84L.Bucur,Gabriela Bucur, A.-G.Moise, Cristina PopescuFinite Element Method Applied to Mathematical Modelling of the Hydrogen Diffusion Process in Metals...........................................87Delia Nica-BadeaControl of Pungent Active Principles from Indigenous Peppers, by Chromatographic Techniques Coupled withMass Spectrometry, as a Method of Identifying and Confirming the Separated Compounds..................................................................92Oana Tanculescu, A.Doloca, Raluca-Maria Vieriu, Florentina Mocanu, Gianina Iovan, Gabriela Ifteni,Silvia Martu, Nicoleta IoanidPhysical and Mechanical Characterization of Different Fiber-reinforcedComposite Systems Used in Fixed Prosthesis........................................................................................................................................96

G.Veisa, Mihaela-Dora Donciu, L.Segall, Loredana Hurjui, I.Nistor, Irina Georgeta Ursarescu, Silvia Martu,S.L.Burlea, Sorina Mihaela SolomonAlbumin as a Prognostic Factor for Malnutrition and Inflammationin Chronic Kidney Disease..............................................................103Elena Manaila, Mariana Daniela Berechet, Maria Daniela Stelescu,Gabriela Craciun, D.E.Mihaescu, B.Purcareanu,I.Calinescu,A.Fudulu, M.RaduComparation Between Chemical Compositions of Some Essential Oils Obtainedby Hydrodistillation from Citrus Peels....................................................................................................................................................106Lenuta-Maria Suta, Gabriela Vlase, T.Vlase, T. Olariu, I.Ledeti, Ionela Belu, C.Ivan, C.-A.Sarau,Germaine Savoiu-Balint, Lavinia Stelea, Adriana LedetiSolid State Stability of Cholesterol. Preliminary kinetic analysis.................................................................................................................113Diana Camelia Bonte, Angela Boglut, C.Duta, Izabella Petre, Elena Bernad, Cristina Vlad Daliborca, R.E.Iacob,Mirabela Dima, Daniela IacobThe Harmful Effects of Smoking during Pregnancy and Correlating Lead and Selenium Levelsin Mothers and Premature Fetuses.........................................................................................................................................................116S.Avram, Stefana Avram, M.Raica, Cristina DeheleanEffective Predictor of Human Mast Cell Tryptase Inhibitors........................................................................................................................119Liliana Porojan, Cristina Savencu, S.PorojanApplications of Heat-pressed Ceramics for Single Tooth Restorations.......................................................................................................123Dorina Mantu, Vasilichia Antoci, Violeta Vasilache, Catalina Mihaela LucaStructure and Anticancer Activity of Some bis-pyridazine Derivatives........................................................................................................127C.Ilie, I.Golet, Mihaela Craciunescu, Elena Hogea, Roxana Popescu,F .G.HorhatChemical Composition and Antimicrobial Activity of Essential Oil of Western Romanian Salvia officinalis..........................................131Doina Lutic, I.CretescuOptimization Study of Rhodamine 6G Removal from Aqueous Solutions by Photocatalytic Oxidation..............................................134Ali Al-Ali, Mihaela Bombos, Daniela Angela Buzoianu,V.Matei, Raluca Dragomir, T.Juganaru, D.BombosHydrotreating of Coker Gas Oil in Single and Double Catalytic Layer........................................................................................................139Danuta Ghita, D.Stanica Ezeanu, Diana Cursaru, P.RoscaHydrogen Production by Steam Reforming of Bioethanol over Pt Based Catalysts.................................................................................145Ali A.A.Al Janabi, Oana Cristina Parvulescu, T.Dobre, Violeta Alexandra IonPervaporation of Aqueous Ethanol Solutions Through Pure and Composite Cellulose Membranes....................................................150Liana Bogatu, Raluca Elena Dragomir, P. RoscaEffiency of Antioxidant Additives Mixed in Vegetable Oils..........................................................................................................................157G.M.Nitulescu, S.G.Soriga, Laura Ileana Socea, O.T.Olaru, V.PlesuStructure-activity Relationship and Chemoinformatic Analysis of the AnticancerProfile of an Aminopyrazole Derivative................................................................................................................................................. 162Cristina Orbeci, Cristina Modrogan, Annette Madelene DancilaDegradation of Pharmaceutical Effluents by Photo-assisted Techniques.................................................................................................166Camelia Vidita Gurban, Florina-Maria Andrica, C.Citu, Elena Hogea, I.Marincu, Marioara Cornianu,O.A.MederleCombined Therapies in Abdominal Actinomycosis....................................................................................................................................171Lucia Varga, A.E.Cioabla, Ioana IonelComparative Determination of Cofermentation Using Residual Watersfor Biogas Production at Small Scale......................................................................................................................................................174E.S.Barca, Lucia Carmen Trinca, Mihaela Filipescu, Maria Dinescu, Adriana-Gabriela Plaiasu,Marioara Abrudeanu, R.LeataInfluence of CeO2 Thickness Layer Deposited on the 945A Steel Substrate Concerning the Corrosion Process................................177T.D.Danciu, E.DanciuSeparation of Heterogenous Solid-Fluid Mixtures. IX. Filtration theory withnew flowing models through packed beds..........................................................................................................................................182Gabriela Gurau, K.Earar, Malina Coman, C.A.Dinu, Camelia Busila, D.C.Voicu,Luana Andreea Macovei, Alina Mihaela Calin, Manuela ArbuneThe Electrophoretic Patterns of Serum Proteins in Children.......................................................................................................................190Elena Doina Dascalu, I.Bostan, C.Popescu, I.-B.Robu, C.Mihai, B.Firtescu, C.IstrateThe Influence of Buisness Cycles on the European Chemical Industry....................................................................................................195C.D. Radu, Oana Parteni, I. G.Sandu, Gabriela Lisa, C. Munteanu, V.V. LupuSpecific Characterization of a Multilayer Biomaterial Controlled Release of Tacrolimus.............................................................199

! ! ! ! ! Societatea de Chimie din România! ! ! ! ! SYSCOM 18 Bucureºti! ! ! ! ! SC Biblioteca Chimiei SA

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Bucharest - RomaniaChem. Abs.: RCBUAU 67 (1) (1 - 204)

ISSN 0034-7752Vol. 67, no. 1, Ianuarie, 2016

CUPRINS

F.H.Kamar, Aurelia Cristina Nechifor, Gh.Nechifor, M.H.Sallomi, A.D.JasemStudiul sistemelor simple si binare pentru indepartarea ionilor de Cu si Cd din solutii apoaseutilizand frunze de varza ca material bioabsorbant ...................................................................................................................................1Mariana Deleanu, Gabriela M.Sanda, Camelia S.Stancu, Mona E.Popa, Anca V.SimaProfilul acizilor grasi si al unor produsi lipidici de peroxidare din lipoproteinele de joasa densitatedin aterogenele umane................................................................................................................................................................................8L.Tarko, Anca HirtopeanuStudiul QSAR privind activitatea inhibitorie a unor iminozaharuri inhibitori ai α-glucozidazei..................................................................13Laura-Ileana Socea, G.Saramet, C.Draghici, Stefania-Felicia Barbuceanu, Diana Carolina Ilies, B.SoceaCercetari privind sinteza si caracterizarea unor noi 1,3,4-oxadiazoli jumatati de 5H-dibenzo[a,d][7]anulena...................................17C.I.Tanase, F.Cocu, C.Draghici, M.T.Caproiu, Catalina Negut, Denisa Ioana UdeanuPrecusori acilati ai analogilor PGF2α ............................................................................................................................................................20M.Ruse, Anca Angela Athanasiu, Loti Cornelia Oproiu, C.FilipescuStudiul relatiei structura-culoare in clasa colorantilor azoici acizi crom-complecsi (1:1) preformatice contin grupa sulfonica in componenta de diazotare.......................................................................................................................26Georgeta Pavalache, V.Dorneanu, Antoanela PopescuO noua metoda HPLC pentru separarea si determinarea cantitativa a loratidinei ......................................................................................30Alexandra Pica, A.FicaiO noua generatie de materiale peliculogene modificate, cu proprietati antibacteriene .........................................................................34B.Tita, C.Morgovan, D.Tita, Teodora Alina NeagMedicamente antiinflamatoare care interactioneaza cu ionul metalic Zn(II). Sinteza, caracterizareasi comportarea termica a complexului cu ketoprofen ...........................................................................................................................38Gh.Romanescu, Mariana Iosub, I.Sandu, I.Minea, A.Enea, D.Dascalita, Oana-Elena HapciucAnaliza spatio-temporala a calitatii apelor din raul Ozana ..................................................................................................................42G.A.Zainescu, Rodica Roxana Constantinescu, P.Voicu, Dana C.DeselnicuStudiul capacitatii de levigatie a nutrientilor din solurile tratate cu biopolimeri care contin titan .........................................................48R.Guzman-Cabrera, J.R.Guzman-Sepulveda, A.Gonzales Parada, J.Rosales Garcia, M.Torres Cisneros, D.BaleanuProcesarea digitala a imaginilor termografice pentru aplicatii medicale ......................................................................................................53D.Acatrinei, Carmen Gentimir(Amititeloaie), Catalina Zaharia(Avram), Cristina Oana Raducanu,Geanina Bogza, Liliana Chelaru, D.Vasincu, Otilia Boisteanu, M.CostuleanuRelatii intre efectele biochimice ale agonistilor NR4A1 si apoptoza linfocitelor pre-B .........................................................................57L.G.Bahrin, H.Hopf, P.G.Jones, K.Earar, L.M.BirsaSinteza si caracterizarea structurala a unui nou N,N-dietilaminacarboditioat de fenacil ce contine iod ......................................61Lavinia Madalina Micu, D.I.Petanec, Maria Dumitrela Iosub-Ciur, S.Andrian, Ramona Amina PopoviciContinutul de metale grele in frunzele si fructele de padureHippophae rhamnoides si Rubus Fruticosus din deseurile miniere ............................................................................................................64Roxana Popescu, Vlad C.Daliborca, Adinela Cimporescu, Cristina S.Vlad, Doina Verdes, Dorica Botau,Marioara N.Filimon, I.Pauliuc, C.Citu, V.DumitrascuProprietatile chimice si efectele antitumorale in vitro ale extractului de castravete amar in diferiti solventi.........................................69Vasilica Popescu, Irina Crina Anca Sandu, G.PopescuEvaluarea colorimetrica a modificarilor chimice generate prin functionalizarea PNA-uluiin mediu acid / bazic si grefarea cu chitosan ...............................................................................................................................................74M.F.Berceanu, Iulia Pinzaru, T.Bratu, Z.Crainiceanu, Lavinia Ceuta, F.Borcan, Dorina Coricovac, C.CituEvolutia melanomului la soarecele femela. O evaluarea noninvaziva ...............................................................................................81Lenuta-Maria Suta, Gabriela Vlase, T.Vlase, Germaine Savoiu-Balint, T.Olariu, Ionela Belu, Adriana Ledeti,M.-S.Murariu, Lavinia Stelea, I. LedetiCaracterizarea termica a colesterolului in aer fata de atmosfera de azot ...................................................................................................84L.Bucur,Gabriela Bucur, A.-G.Moise, Cristina PopescuAplicarea metodei cu elemente finite la modelarea matematica a procesuluide difuzie a hidrogenului in metale ..........................................................................................................................................................87Delia Nica-BadeaAnaliza principiilor active pungente din ardeii indigeni prin tehnici cromatografice cuplatecu spectrometrie de masa ca metoda de identificare si confirmare a separarii compusilor ..............................................................92

Oana Tanculescu, A.Doloca, Raluca-Maria Vieriu, Florentina Mocanu, Gianina Iovan, Gabriela Ifteni,Silvia Martu, Nicoleta IoanidCaracterizarea fizica si mecanica a diferitelor sisteme din compozit ranforsat cu fibre utilizate in protezarea fixa ............................96G.Veisa, Mihaela-Dora Donciu, L.Segall, Loredana Hurjui, I.Nistor, Irina Georgeta Ursarescu, Silvia Martu,S.L.Burlea, Sorina Mihaela SolomonAlbumina ca factor de pronosticare a malnutritiei si inflamatiilor in afectiunile cronice la copii.......................................................103Elena Manaila, Mariana Daniela Berechet, Maria Daniela Stelescu,Gabriela Craciun,D.E.Mihaescu, B.Purcareanu,I.Calinescu,A.Fudulu, M.RaduComparatie intre compozitia chimica a unor uleiuri esentiale obtinute prin hidrodistilare din coji de citrice .........................106Lenuta-Maria Suta, Gabriela Vlase, T.Vlase, T. Olariu, I.Ledeti, Ionela Belu, C.Ivan, C.-A.Sarau,Germaine Savoiu-Balint, Lavinia Stelea, Adriana LedetiStabilitatea colesterolului in stare solida . Analiza cinetica preliminara..................................................................................................113Diana Camelia Bonte, Angela Boglut, C.Duta, Izabella Petre, Elena Bernad, Cristina Vlad Daliborca, R.E.Iacob,Mirabela Dima, Daniela IacobEfectul nociv al fumatului in timpul sarcinii si corelarea nivelurilor de Pb si Se la mame si fetusii prematuri...........................116S.Avram, Stefana Avram, M.Raica, Cristina DeheleanStudiul inhibitorilor triptazei eliberata de mastocitele umane .............................................................................................................119Liliana Porojan, Cristina Savencu, S.PorojanAplicarea ceramicilor presate la cald pentru restaurarea unui singur dinte .............................................................................................123Dorina Mantu, Vasilichia Antoci, Violeta Vasilache, Catalina Mihaela LucaStructura si activitatea anticancerigena a unor derivati ai bis-piridazinei ...............................................................................................127C.Ilie, I.Golet, Mihaela Craciunescu, Elena Hogea, Roxana Popescu,F .G.HorhatCompozitia chimica si activitatea antimicrobiana a uneiurilor esentiale de salvie din vestul Romaniei ....................................131Doina Lutic, I.CretescuStudiu optimizarii indepartarii rhodaminei 6G din solutiile apoase prin oxidare fotocatalitica ..............................................................134Ali Al-Ali, Mihaela Bombos, Daniela Angela Buzoianu,V.Matei, Raluca Dragomir, T.Juganaru, D.BombosHidrocracarea motorieni de cocsarea in strat catalitic simplu si dublu ........................................................................................................139Danuta Ghita, D.Stanica Ezeanu, Diana Cursaru, P.RoscaObtinerea hidrogenului prin reformarea cu abur a bioetanolului pe catalizatori pe baza de Pt ............................................................145Ali A.A.Al Janabi, Oana Cristina Parvulescu, T.Dobre, Violeta Alexandra IonPervaporarea solutiilor apoase de etanol cu ajutorul membranelor celulozice pure si compozite.......................................................150Liana Bogatu, Raluca Elena Dragomir, P. RoscaEficienta aditivilor antioxidanti adaugati in uleiurile vegetale ..................................................................................................................157G.M.Nitulescu, S.G.Soriga, Laura Ileana Socea, O.T.Olaru, V.PlesuRelatia stuctura - activitate si analiza chemoinformatica a profilului anticanceros a unui derivat aminotirazolic ........................ 162Cristina Orbeci, Cristina Modrogan, Annette Madelene DancilaDegradarea efluentilor farmaceutici prin tehnici fotoasistate ...................................................................................................................166Camelia Vidita Gurban, Florina-Maria Andrica, C.Citu, Elena Hogea, I.Marincu,Marioara Cornianu, O.A.MederleTerapii combinate pentru tratatrea actinomicozelor abdominale ..............................................................................................................171Lucia Varga, A.E.Cioabla, Ioana IonelDetermianrea comparativa a cofermentatiei utilizand ape reziduale de la producerea biogazului la scara mica..............................174E.S.Barca, Lucia Carmen Trinca, Mihaela Filipescu, Maria Dinescu, Adriana-Gabriela Plaiasu,Marioara Abrudeanu, R.LeataInfluenta grosimii stratului de CeO2 depus pe substratul de otel 945A asupra procesului de coroziune .......................................177T.D.Danciu, E.DanciuSepararea amestecurilor heterogene solid-fluid. IX. Teoria filtrarii cu noi modele de curgere prin paturi impachetate...................182Gabriela Gurau, K.Earar, Malina Coman, C.A.Dinu, Camelia Busila, D.C.Voicu,Luana Andreea Macovei, Alina Mihaela Calin, Manuela ArbuneModele electroforetice ale proteinelor serice la copii .......................................................................................................................190Elena Doina Dascalu, I.Bostan, C.Popescu, I.-B.Robu, C.Mihai, B.Firtescu, C.IstrateInfluenta cercurilor de afaceri asupra industriei chimice europene ......................................................................................................195C.D. Radu, Oana Parteni, I. G. Sandu, Gabriela Lisa, C. Munteanu, V.V. LupuCaracterizari specifice ale unui biomaterial multistrat pentru eliberarea controlata a tacrolimusului.............................................199

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