extraccion cu y mn con oxina large

8/13/2019 Extraccion Cu y Mn Con Oxina Large

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-3.00

-2.00

-1.00

0.00

1.00

2.00

3.00

0 1 2 3 4 5 6 7 8 9 10 11 12 13 14

LogD

(L)

pH

Diagrama de Log D = f(pH) para el agente quelante L

Log D


2/38

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

Diagrama de pLen funcin del pH ( PERFIL DE EXTRACCION) para el agente quelante L

pL


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0

10

20

30

40

50

60

70

80

90

100

0 1 2 3 4 5 6 7 8 9 10 11 12 13 14

Grafica de % Extraccin (%E) de el agente quelante Lorganico en funcin pH)

%E (L')


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5/38

0

10

20

30

40

50

60

70

80

90

100

0 1 2 3 4 5 6 7 8 9 10 11 12 13 14

%EMLnorg

Grafica de % Extraccin (%E) de MLn organico en funcin pH

%E MLn org


6/38

DATOS DE CMLn

Log Kd 2.6 Kd 398.107171 LOG BETA 1

H2L LOG BETA 2

pKa 1 5 Ka 1 0.00001 LOG BETA 3

pKa 2 9.7 Ka 2 1.9953E-10 LOG BETA 4

LOG BETA 5

L' inicial organico 1.00E-02 LOG BETA 6

L' inicila acuoso 2.00E-04

Volumen Forg 5Volumen Facuo 10

r 0.5

n* 0.052

pH H+ D (L ') Log D %E (L ') pL alpha L (H)

0 1.00E+00 3.98E-03 -2.40 0.20 2.28 5.01E+14

0.1 7.94E-01 5.01E-03 -2.30 0.25 2.29 3.16E+140.2 6.31E-01 6.31E-03 -2.20 0.31 2.29 2.00E+14

0.3 5.01E-01 7.94E-03 -2.10 0.40 2.29 1.26E+14

0.4 3.98E-01 1.00E-02 -2.00 0.50 2.29 7.94E+13

0.5 3.16E-01 1.26E-02 -1.90 0.63 2.29 5.01E+13

0.6 2.51E-01 1.58E-02 -1.80 0.79 2.29 3.16E+13

0.7 2.00E-01 2.00E-02 -1.70 0.99 2.29 2.00E+13

0.8 1.58E-01 2.51E-02 -1.60 1.24 2.29 1.26E+13

0.9 1.26E-01 3.16E-02 -1.50 1.56 2.29 7.94E+12

1 1.00E-01 3.98E-02 -1.40 1.95 2.29 5.01E+12

1.1 7.94E-02 5.01E-02 -1.30 2.44 2.29 3.16E+12

1.2 6.31E-02 6.31E-02 -1.20 3.06 2.30 2.00E+12

1 3 5 01E 02 7 94E 02 1 10 3 82 2 30 1 26E+12

DATOS PARA EL AGENTE EXTRACTANTE (L)

Hoja de Calculo para la Extraccion de Quelatos meatl icos MLn

*Solo cambiar los valores en rojo


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3.3 5.01E-04 7.79E+00 0.89 79.57 2.97 1.28E+08

3.4 3.98E-04 9.75E+00 0.99 82.99 3.05 8.14E+07

3.5 3.16E-04 1.22E+01 1.09 85.92 3.14 5.17E+073.6 2.51E-04 1.52E+01 1.18 88.40 3.22 3.29E+07

3.7 2.00E-04 1.90E+01 1.28 90.48 3.31 2.10E+07

3.8 1.58E-04 2.36E+01 1.37 92.20 3.39 1.34E+07

3.9 1.26E-04 2.93E+01 1.47 93.61 3.48 8.57E+06

4 1.00E-04 3.62E+01 1.56 94.76 3.56 5.51E+06

4.1 7.94E-05 4.45E+01 1.65 95.70 3.65 3.56E+06

4.2 6.31E-05 5.45E+01 1.74 96.46 3.73 2.31E+06

4.3 5.01E-05 6.62E+01 1.82 97.07 3.82 1.51E+06

4.4 3.98E-05 7.99E+01 1.90 97.56 3.90 9.94E+054.5 3.16E-05 9.56E+01 1.98 97.95 3.97 6.60E+05

4.6 2.51E-05 1.13E+02 2.05 98.27 4.05 4.42E+05

4.7 2.00E-05 1.33E+02 2.12 98.52 4.11 3.00E+05

4.8 1.58E-05 1.54E+02 2.19 98.72 4.18 2.05E+05

4.9 1.26E-05 1.76E+02 2.25 98.88 4.23 1.43E+05

5 1.00E-05 1.99E+02 2.30 99.01 4.29 1.00E+05

5.1 7.94E-06 2.22E+02 2.35 99.11 4.33 7.14E+04

5.2 6.31E-06 2.44E+02 2.39 99.19 4.37 5.16E+04

5.3 5.01E-06 2.65E+02 2.42 99.25 4.41 3.77E+045.4 3.98E-06 2.85E+02 2.45 99.30 4.44 2.79E+04

5.5 3.16E-06 3.02E+02 2.48 99.34 4.47 2.09E+04

5.6 2.51E-06 3.18E+02 2.50 99.38 4.49 1.58E+04

5.7 2.00E-06 3.32E+02 2.52 99.40 4.51 1.20E+04

5.8 1.58E-06 3.44E+02 2.54 99.42 4.52 9.20E+03

5.9 1.26E-06 3.54E+02 2.55 99.44 4.53 7.10E+03

6 1.00E-06 3.62E+02 2.56 99.45 4.54 5.51E+03

6.1 7.94E-07 3.69E+02 2.57 99.46 4.55 4.30E+03

6.2 6.31E-07 3.74E+02 2.57 99.47 4.56 3.36E+03

6.3 5.01E-07 3.79E+02 2.58 99.48 4.56 2.64E+03

6.4 3.98E-07 3.83E+02 2.58 99.48 4.57 2.08E+03

6 5 3 16E 07 3 86E+02 2 59 99 48 4 57 1 64E+03


8/38

8.5 3.16E-09 3.74E+02 2.57 99.47 4.56 1.69E+01

8.6 2.51E-09 3.69E+02 2.57 99.46 4.55 1.36E+01

8.7 2.00E-09 3.62E+02 2.56 99.45 4.54 1.10E+018.8 1.58E-09 3.54E+02 2.55 99.44 4.53 8.94E+00

8.9 1.26E-09 3.44E+02 2.54 99.42 4.52 7.31E+00

9 1.00E-09 3.32E+02 2.52 99.40 4.51 6.01E+00

9.1 7.94E-10 3.18E+02 2.50 99.38 4.49 4.98E+00

9.2 6.31E-10 3.02E+02 2.48 99.34 4.47 4.16E+00

9.3 5.01E-10 2.85E+02 2.45 99.30 4.44 3.51E+00

9.4 3.98E-10 2.65E+02 2.42 99.25 4.41 3.00E+00

9.5 3.16E-10 2.44E+02 2.39 99.19 4.37 2.58E+00

9.6 2.51E-10 2.22E+02 2.35 99.11 4.33 2.26E+009.7 2.00E-10 1.99E+02 2.30 99.01 4.29 2.00E+00

9.8 1.58E-10 1.76E+02 2.25 98.88 4.23 1.79E+00

9.9 1.26E-10 1.54E+02 2.19 98.72 4.18 1.63E+00

10 1.00E-10 1.33E+02 2.12 98.52 4.11 1.50E+00

10.1 7.94E-11 1.13E+02 2.05 98.27 4.05 1.40E+00

10.2 6.31E-11 9.56E+01 1.98 97.95 3.97 1.32E+00

10.3 5.01E-11 7.99E+01 1.90 97.56 3.90 1.25E+00

10.4 3.98E-11 6.62E+01 1.82 97.07 3.82 1.20E+00

10.5 3.16E-11 5.45E+01 1.74 96.46 3.73 1.16E+0010.6 2.51E-11 4.45E+01 1.65 95.70 3.65 1.13E+00

10.7 2.00E-11 3.62E+01 1.56 94.76 3.56 1.10E+00

10.8 1.58E-11 2.93E+01 1.47 93.61 3.48 1.08E+00

10.9 1.26E-11 2.36E+01 1.37 92.20 3.39 1.06E+00

11 1.00E-11 1.90E+01 1.28 90.48 3.31 1.05E+00

11.1 7.94E-12 1.52E+01 1.18 88.40 3.22 1.04E+00

11.2 6.31E-12 1.22E+01 1.09 85.92 3.14 1.03E+00

11.3 5.01E-12 9.75E+00 0.99 82.99 3.05 1.03E+00

11.4 3.98E-12 7.79E+00 0.89 79.57 2.97 1.02E+00

11.5 3.16E-12 6.21E+00 0.79 75.64 2.90 1.02E+00

11.6 2.51E-12 4.95E+00 0.69 71.22 2.82 1.01E+00

11 7 2 00E 12 3 94E+00 0 60 66 34 2 76 1 01E+00


9/38

13.7 2.00E-14 3.98E-02 -1.40 1.95 2.29 1.00E+00

13.8 1.58E-14 3.16E-02 -1.50 1.56 2.29 1.00E+00

13.9 1.26E-14 2.51E-02 -1.60 1.24 2.29 1.00E+0014 1.00E-14 2.00E-02 -1.70 0.99 2.29 1.00E+00


10/38

OMP. DE M CON L EN FASE ACUOSA DATOS DE COMP. DE M CON OH EN FASE ACUMOHn

-10 BETA 1 1E-10 LOG BETA 1 11 BETA 1

-10 BETA 2 1E-10 LOG BETA 2 21.7 BETA 2

-10 BETA 3 1E-10 LOG BETA 3 -10 BETA 3




L l ib re al pha M (L ) LOG al pha M(L ) OH al pha M (OH ) LOGal phaM(OH)

1.04E-17 1.00E+00 0.00 1.00E-14 1.00E+00 0.00

1.64E-17 1.00E+00 0.00 1.26E-14 1.00E+00 0.002.60E-17 1.00E+00 0.00 1.58E-14 1.00E+00 0.00

4.11E-17 1.00E+00 0.00 2.00E-14 1.00E+00 0.00

6.51E-17 1.00E+00 0.00 2.51E-14 1.00E+00 0.00

1.03E-16 1.00E+00 0.00 3.16E-14 1.00E+00 0.00

1.63E-16 1.00E+00 0.00 3.98E-14 1.00E+00 0.00

2.58E-16 1.00E+00 0.00 5.01E-14 1.01E+00 0.00

4.08E-16 1.00E+00 0.00 6.31E-14 1.01E+00 0.00

6.44E-16 1.00E+00 0.00 7.94E-14 1.01E+00 0.00

1.02E-15 1.00E+00 0.00 1.00E-13 1.01E+00 0.00

1.60E-15 1.00E+00 0.00 1.26E-13 1.01E+00 0.01

2.53E-15 1.00E+00 0.00 1.58E-13 1.02E+00 0.01

3 97E 15 1 00E+00 0 00 2 00E 13 1 02E+00 0 01


11/38

8.27E-12 1.00E+00 0.00 2.00E-11 4.99E+00 0.70

1.09E-11 1.00E+00 0.00 2.51E-11 6.67E+00 0.82

1.42E-11 1.00E+00 0.00 3.16E-11 9.17E+00 0.961.83E-11 1.00E+00 0.00 3.98E-11 1.29E+01 1.11

2.36E-11 1.00E+00 0.00 5.01E-11 1.86E+01 1.27

3.03E-11 1.00E+00 0.00 6.31E-11 2.73E+01 1.44

3.88E-11 1.00E+00 0.00 7.94E-11 4.06E+01 1.61

4.94E-11 1.00E+00 0.00 1.00E-10 6.11E+01 1.79

6.28E-11 1.00E+00 0.00 1.26E-10 9.30E+01 1.97

7.97E-11 1.00E+00 0.00 1.58E-10 1.43E+02 2.15

1.01E-10 1.00E+00 0.00 2.00E-10 2.20E+02 2.34

1.28E-10 1.00E+00 0.00 2.51E-10 3.42E+02 2.531.61E-10 1.00E+00 0.00 3.16E-10 5.34E+02 2.73

2.04E-10 1.00E+00 0.00 3.98E-10 8.35E+02 2.92

2.57E-10 1.00E+00 0.00 5.01E-10 1.31E+03 3.12

3.25E-10 1.00E+00 0.00 6.31E-10 2.06E+03 3.31

4.09E-10 1.00E+00 0.00 7.94E-10 3.24E+03 3.51

5.16E-10 1.00E+00 0.00 1.00E-09 5.11E+03 3.71

6.50E-10 1.00E+00 0.00 1.26E-09 8.07E+03 3.91

8.19E-10 1.00E+00 0.00 1.58E-09 1.27E+04 4.11

1.03E-09 1.00E+00 0.00 2.00E-09 2.02E+04 4.301.30E-09 1.00E+00 0.00 2.51E-09 3.19E+04 4.50

1.64E-09 1.00E+00 0.00 3.16E-09 5.04E+04 4.70

2.06E-09 1.00E+00 0.00 3.98E-09 7.98E+04 4.90

2.60E-09 1.00E+00 0.00 5.01E-09 1.26E+05 5.10

3.27E-09 1.00E+00 0.00 6.31E-09 2.00E+05 5.30

4.12E-09 1.00E+00 0.00 7.94E-09 3.17E+05 5.50

5.18E-09 1.00E+00 0.00 1.00E-08 5.02E+05 5.70

6.53E-09 1.00E+00 0.00 1.26E-08 7.96E+05 5.90

8.22E-09 1.00E+00 0.00 1.58E-08 1.26E+06 6.10

1.03E-08 1.00E+00 0.00 2.00E-08 2.00E+06 6.30

1.30E-08 1.00E+00 0.00 2.51E-08 3.16E+06 6.50

1 64E 08 1 00E+00 0 00 3 16E 08 5 02E+06 6 70


12/38

1.64E-06 1.00E+00 0.00 3.16E-06 5.01E+10 10.70

2.06E-06 1.00E+00 0.00 3.98E-06 7.94E+10 10.90

2.60E-06 1.00E+00 0.00 5.01E-06 1.26E+11 11.10

3.27E-06 1.00E+00 0.00 6.31E-06 2.00E+11 11.30

4.12E-06 1.00E+00 0.00 7.94E-06 3.16E+11 11.50

5.18E-06 1.00E+00 0.00 1.00E-05 5.01E+11 11.70

6.52E-06 1.00E+00 0.00 1.26E-05 7.94E+11 11.90

8.21E-06 1.00E+00 0.00 1.58E-05 1.26E+12 12.10

1.03E-05 1.00E+00 0.00 2.00E-05 2.00E+12 12.30

1.30E-05 1.00E+00 0.00 2.51E-05 3.16E+12 12.50

1.63E-05 1.00E+00 0.00 3.16E-05 5.01E+12 12.70

2.06E-05 1.00E+00 0.00 3.98E-05 7.94E+12 12.902.59E-05 1.00E+00 0.00 5.01E-05 1.26E+13 13.10

3.25E-05 1.00E+00 0.00 6.31E-05 2.00E+13 13.30

4.09E-05 1.00E+00 0.00 7.94E-05 3.16E+13 13.50

5.14E-05 1.00E+00 0.00 1.00E-04 5.01E+13 13.70

6.45E-05 1.00E+00 0.00 1.26E-04 7.94E+13 13.90

8.09E-05 1.00E+00 0.00 1.58E-04 1.26E+14 14.10

1.01E-04 1.00E+00 0.00 2.00E-04 2.00E+14 14.30

1.27E-04 1.00E+00 0.00 2.51E-04 3.16E+14 14.50

1.59E-04 1.00E+00 0.00 3.16E-04 5.01E+14 14.701.99E-04 1.00E+00 0.00 3.98E-04 7.94E+14 14.90

2.48E-04 1.00E+00 0.00 5.01E-04 1.26E+15 15.10

3.08E-04 1.00E+00 0.00 6.31E-04 2.00E+15 15.30

3.82E-04 1.00E+00 0.00 7.94E-04 3.16E+15 15.50

4.72E-04 1.00E+00 0.00 1.00E-03 5.01E+15 15.70

5.80E-04 1.00E+00 0.00 1.26E-03 7.94E+15 15.90

7.10E-04 1.00E+00 0.00 1.58E-03 1.26E+16 16.10

8.63E-04 1.00E+00 0.00 2.00E-03 2.00E+16 16.30

1.04E-03 1.00E+00 0.00 2.51E-03 3.16E+16 16.50

1.25E-03 1.00E+00 0.00 3.16E-03 5.01E+16 16.70

1.48E-03 1.00E+00 0.00 3.98E-03 7.94E+16 16.90

1 73E 03 1 00E+00 0 00 5 01E 03 1 26E+17 17 10


13/38

5.10E-03 1.00E+00 0.00 5.01E-01 1.26E+21 21.10

5.12E-03 1.00E+00 0.00 6.31E-01 2.00E+21 21.30

5.14E-03 1.00E+00 0.00 7.94E-01 3.16E+21 21.50

5.15E-03 1.00E+00 0.00 1.00E+00 5.01E+21 21.70


14/38

SA DATOS DE COMP. DE M CON X EN FASE ACUOSA DATOS DE LA EX

MXn

1E+11 LOG BETA 1 -10 BETA 1 1E-10

5.01187E+21 LOG BETA 2 -10 BETA 2 1E-10

1E-10 LOG BETA 3 -10 BETA 3 1E-10 n

1E-10 LOG BETA 4 -10 BETA 4 1E-10 Log K extraccion

1E-10 LOG BETA 5 -10 BETA 5 1E-10

1E-10 LOG BETA 6 -10 BETA 6 1E-10

H4X

LOG BETA 1 -10 BETA 1 1E-10LOG BETA 2 -10 BETA 2 1E-10

LOG BETA 3 -10 BETA 3 1E-10

LOG BETA 4 -10 BETA 4 1E-10

Conc total X 0

alp ha X (H) X l ib re alp haM(X) L OGalp haM(X) p L libre

1.00E+00 0.00E+00 1.00E+00 0.00 -16.985

1.00E+00 0.00E+00 1.00E+00 0.00 -16.7851.00E+00 0.00E+00 1.00E+00 0.00 -16.585

1.00E+00 0.00E+00 1.00E+00 0.00 -16.386

1.00E+00 0.00E+00 1.00E+00 0.00 -16.186

1.00E+00 0.00E+00 1.00E+00 0.00 -15.987

1.00E+00 0.00E+00 1.00E+00 0.00 -15.787

1.00E+00 0.00E+00 1.00E+00 0.00 -15.588

1.00E+00 0.00E+00 1.00E+00 0.00 -15.389

1.00E+00 0.00E+00 1.00E+00 0.00 -15.191

1.00E+00 0.00E+00 1.00E+00 0.00 -14.993

1.00E+00 0.00E+00 1.00E+00 0.00 -14.795

1.00E+00 0.00E+00 1.00E+00 0.00 -14.598

1 00E+00 0 00E+00 1 00E+00 0 00 14 401

M + n


15/38

1.00E+00 0.00E+00 1.00E+00 0.00 -11.082

1.00E+00 0.00E+00 1.00E+00 0.00 -10.964

1.00E+00 0.00E+00 1.00E+00 0.00 -10.849

1.00E+00 0.00E+00 1.00E+00 0.00 -10.737

1.00E+00 0.00E+00 1.00E+00 0.00 -10.626

1.00E+00 0.00E+00 1.00E+00 0.00 -10.518

1.00E+00 0.00E+00 1.00E+00 0.00 -10.412

1.00E+00 0.00E+00 1.00E+00 0.00 -10.306

1.00E+00 0.00E+00 1.00E+00 0.00 -10.202

1.00E+00 0.00E+00 1.00E+00 0.00 -10.099

1.00E+00 0.00E+00 1.00E+00 0.00 -9.996

1.00E+00 0.00E+00 1.00E+00 0.00 -9.8941.00E+00 0.00E+00 1.00E+00 0.00 -9.792

1.00E+00 0.00E+00 1.00E+00 0.00 -9.691

1.00E+00 0.00E+00 1.00E+00 0.00 -9.589

1.00E+00 0.00E+00 1.00E+00 0.00 -9.489

1.00E+00 0.00E+00 1.00E+00 0.00 -9.388

1.00E+00 0.00E+00 1.00E+00 0.00 -9.287

1.00E+00 0.00E+00 1.00E+00 0.00 -9.187

1.00E+00 0.00E+00 1.00E+00 0.00 -9.087

1.00E+00 0.00E+00 1.00E+00 0.00 -8.9861.00E+00 0.00E+00 1.00E+00 0.00 -8.886

1.00E+00 0.00E+00 1.00E+00 0.00 -8.786

1.00E+00 0.00E+00 1.00E+00 0.00 -8.686

1.00E+00 0.00E+00 1.00E+00 0.00 -8.586

1.00E+00 0.00E+00 1.00E+00 0.00 -8.485

1.00E+00 0.00E+00 1.00E+00 0.00 -8.385

1.00E+00 0.00E+00 1.00E+00 0.00 -8.285

1.00E+00 0.00E+00 1.00E+00 0.00 -8.185

1.00E+00 0.00E+00 1.00E+00 0.00 -8.085

1.00E+00 0.00E+00 1.00E+00 0.00 -7.985

1.00E+00 0.00E+00 1.00E+00 0.00 -7.885

1 00E+00 0 00E+00 1 00E+00 0 00 7 785


16/38


17/38

1.00E+00 0.00E+00 1.00E+00 0.00 -2.293

1.00E+00 0.00E+00 1.00E+00 0.00 -2.291

1.00E+00 0.00E+00 1.00E+00 0.00 -2.289

1.00E+00 0.00E+00 1.00E+00 0.00 -2.288


18/38

RACCION MLn

3.000

42.300

L og D" M %E MLn o rg

-8.655 0.00

-8.056 0.00-7.457 0.00

-6.858 0.00

-6.260 0.00

-5.662 0.00

-5.064 0.00

-4.467 0.00

-3.871 0.01

-3.276 0.03

-2.682 0.10

-2.090 0.40

-1.500 1.56

0 912 5 77

L MLn org


19/38


20/38

14.244 100.00

14.344 100.00

14.444 100.00

14.544 100.00

14.644 100.00

14.743 100.00

14.843 100.00

14.943 100.00

15.042 100.00

15.141 100.00

15.240 100.00

15.339 100.0015.438 100.00

15.536 100.00

15.634 100.00

15.732 100.00

15.828 100.00

15.924 100.00

16.019 100.00

16.112 100.00

16.204 100.0016.294 100.00

16.381 100.00

16.465 100.00

16.545 100.00

16.621 100.00

16.690 100.00

16.753 100.00

16.808 100.00

16.853 100.00

16.887 100.00

16.909 100.00

16 916 100 00


21/38

14.322 100.00

14.127 100.00

13.932 100.00

13.735 100.00


22/38

Vol. Fase org 5

Vol. Fase ac 10

r 0.5

%Elimite M 99%Elimite N 1

%S 98

pH Log D" M %E MLn org Log D" M %E MLn org %Elimite M %Elimite N

0 -8.65502813 1.1065E-07 -19.9671822 5.3925E-19 2.29666519 -1.6946052

0.1 -8.05581393 4.397E-07 -19.3678555 2.1435E-18 2.29666519 -1.6946052

0.2 -7.45680271 1.7465E-06 -18.7687027 8.5166E-18 2.29666519 -1.6946052

0.3 -6.85804673 6.933E-06 -18.1697685 3.3822E-17 2.29666519 -1.6946052

0.4 -6.25961162 2.7502E-05 -17.5711091 1.3423E-16 2.29666519 -1.6946052

0.5 -5.66157974 0.00010899 -16.9727947 5.3232E-16 2.29666519 -1.6946052

0.6 -5.06405435 0.00043143 -16.3749137 2.1089E-15 2.29666519 -1.6946052

0.7 -4.46716482 0.00170529 -15.7775765 8.3444E-15 2.29666519 -1.6946052

0.8 -3.87107294 0.00672772 -15.1809211 3.2965E-14 2.29666519 -1.6946052

0.9 -3.2759808 0.02647733 -14.5851194 1.2997E-13 2.29666519 -1.69460521 -2.68214025 0.10384331 -13.9903857 5.1119E-13 2.29666519 -1.6946052

1.1 -2.0898644 0.4048961 -13.3969854 2.0044E-12 2.29666519 -1.6946052

1.2 -1.49954123 1.55814743 -12.8052466 7.8293E-12 2.29666519 -1.6946052

1.3 -0.91164962 5.77417988 -12.215573 3.0437E-11 2.29666519 -1.6946052

1.4 -0.32677769 19.0682645 -11.6284579 1.1763E-10 2.29666519 -1.6946052

1.5 0.25435668 47.3158509 -11.0444998 4.5131E-10 2.29666519 -1.6946052

1.6 0.83088387 77.2069466 -10.4644186 1.7161E-09 2.29666519 -1.6946052

1.7 1.40176022 92.6526987 -9.88906938 6.4551E-09 2.29666519 -1.6946052

1.8 1.9657475 97.8817166 -9.31945413 2.3962E-08 2.29666519 -1.69460521.9 2.52139685 99.4015522 -8.75672543 8.7548E-08 2.29666519 -1.6946052

2 3.06704117 99.8289019 -8.20218023 3.139E-07 2.29666519 -1.6946052

2.1 3.60080033 99.9498799 -7.65723784 1.1009E-06 2.29666519 -1.6946052


23/38

4.3 9.96896553 100 0.99974275 83.3251049 2.29666519 -1.6946052

4.4 10.0844321 100 1.30630638 91.0090007 2.29666519 -1.6946052

4.5 10.1967505 100 1.61154016 95.3361206 2.29666519 -1.6946052

4.6 10.306555 100 1.91570361 97.6291403 2.29666519 -1.6946052

4.7 10.4143549 100 2.21899782 98.8065128 2.29666519 -1.69460524.8 10.5205579 100 2.52156406 99.4017811 2.29666519 -1.6946052

4.9 10.6254895 100 2.82346445 99.7005921 2.29666519 -1.6946052

5 10.7294095 100 3.12462042 99.850115 2.29666519 -1.6946052

5.1 10.8325249 100 3.42464836 99.9248282 2.29666519 -1.6946052

5.2 10.9350007 100 3.7224464 99.9621192 2.29666519 -1.6946052

5.3 11.0369678 100 4.0152015 99.9806917 2.29666519 -1.6946052

5.4 11.1385308 100 4.29619656 99.9898891 2.29666519 -1.6946052

5.5 11.2397725 100 4.55091465 99.9943754 2.29666519 -1.6946052

5.6 11.340759 100 4.75391241 99.9964755 2.29666519 -1.6946052

5.7 11.4415426 100 4.87678133 99.9973439 2.29666519 -1.6946052

5.8 11.5421651 100 4.91161902 99.9975487 2.29666519 -1.6946052

5.9 11.6426594 100 4.87966506 99.9973615 2.29666519 -1.6946052

6 11.7430521 100 4.81009186 99.9969031 2.29666519 -1.6946052

6.1 11.8433638 100 4.72288382 99.9962144 2.29666519 -1.6946052

6.2 11.9436114 100 4.62813366 99.9952916 2.29666519 -1.6946052

6.3 12.0438078 100 4.53028252 99.9941018 2.29666519 -1.6946052

6.4 12.1439635 100 4.43117376 99.9925899 2.29666519 -1.69460526.5 12.244087 100 4.33155502 99.9906796 2.29666519 -1.6946052

6.6 12.3441846 100 4.23172727 99.9882712 2.29666519 -1.6946052

6.7 12.4442617 100 4.13181172 99.9852377 2.29666519 -1.6946052

6.8 12.5443223 100 4.03185752 99.981418 2.29666519 -1.6946052

6.9 12.6443696 100 3.93188489 99.9766093 2.29666519 -1.6946052

7 12.7444062 100 3.83190237 99.9705558 2.29666519 -1.6946052

7.1 12.8444341 100 3.73191371 99.9629357 2.29666519 -1.6946052

7.2 12.9444547 100 3.63192064 99.9533441 2.29666519 -1.6946052

7.3 13.044469 100 3.53192397 99.9412712 2.29666519 -1.69460527.4 13.1444779 100 3.43192405 99.9260761 2.29666519 -1.6946052

7.5 13.2444819 100 3.33192096 99.9069525 2.29666519 -1.6946052

7.6 13.3444812 100 3.23191457 99.8828866 2.29666519 -1.6946052


24/38

9.8 15.5363975 100 1.02380929 84.0809139 2.29666519 -1.6946052

9.9 15.6342896 100 0.92170137 80.6768632 2.29666519 -1.6946052

10 15.7316407 100 0.81905249 76.7239838 2.29666519 -1.6946052

10.1 15.8283137 100 0.71572538 72.2093801 2.29666519 -1.6946052

10.2 15.9241371 100 0.61154883 67.150416 2.29666519 -1.694605210.3 16.0188981 100 0.50630983 61.6016528 2.29666519 -1.6946052

10.4 16.1123324 100 0.39974413 55.658103 2.29666519 -1.6946052

10.5 16.2041135 100 0.29152517 49.4528799 2.29666519 -1.6946052

10.6 16.2938396 100 0.18125129 43.1483597 2.29666519 -1.6946052

10.7 16.3810197 100 0.06843138 36.9216825 2.29666519 -1.6946052

10.8 16.4650577 100 -0.04753061 30.9471668 2.29666519 -1.6946052

10.9 16.5452369 100 -0.16735144 25.3792235 2.29666519 -1.6946052

11 16.6207052 100 -0.29188313 20.3391132 2.29666519 -1.6946052

11.1 16.6904643 100 -0.42212407 15.9075389 2.29666519 -1.6946052

11.2 16.7533648 100 -0.55922349 12.1232853 2.29666519 -1.6946052

11.3 16.8081132 100 -0.70447517 8.98668962 2.29666519 -1.6946052

11.4 16.8532923 100 -0.85929602 6.46610845 2.29666519 -1.6946052

11.5 16.8874033 100 -1.02518507 4.50570111 2.29666519 -1.6946052

11.6 16.9089279 100 -1.20366039 3.0334142 2.29666519 -1.6946052

11.7 16.9164136 100 -1.39617478 1.96861312 2.29666519 -1.6946052

11.8 16.9085726 100 -1.60401579 1.22908885 2.29666519 -1.6946052

11.9 16.8843866 100 -1.82820171 0.73714859 2.29666519 -1.694605212 16.8431994 100 -2.06938894 0.42435973 2.29666519 -1.6946052

12.1 16.7847808 100 -2.32780752 0.23450001 2.29666519 -1.6946052

12.2 16.7093507 100 -2.60323763 0.1245063 2.29666519 -1.6946052

12.3 16.6175563 100 -2.89503206 0.06362994 2.29666519 -1.6946052

12.4 16.5104085 100 -3.20217988 0.03138006 2.29666519 -1.6946052

12.5 16.3891898 100 -3.52339852 0.01497981 2.29666519 -1.6946052

12.6 16.2553505 100 -3.85723784 0.00694548 2.29666519 -1.6946052

12.7 16.1104081 100 -4.20218023 0.00313889 2.29666519 -1.6946052

12.8 15.9558629 100 -4.55672543 0.00138752 2.29666519 -1.694605212.9 15.7931342 100 -4.91945413 0.00060188 2.29666519 -1.6946052

13 15.623519 100 -5.28906938 0.00025698 2.29666519 -1.6946052

13.1 15.4481698 100 -5.66441855 0.00010828 2.29666519 -1.6946052


25/3820

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0 5 10


26/38


27/38


28/38

%E MLn org

%E MLn org

15

Log D" M

Log D" M

%Elimite M

%Elimite N


29/38

-22

-20

-18

-16

-14

-12

-10

-8

-6

-4

-2

0

2

4

6

0 1 2 3 4 5 6 7 8 9 10 11 12 13 14

Log D" Cu

Log D" Mn

Log D" Limite M"

Log D" limite N"


30/38

0

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40

50

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70

80

90

100

0 1 2 3 4 5 6 7 8 9 10 11 12 13 14

%E Cu (II)"

%E Mn(II)"


31/38

Vol. Fase org 5

Vol. Fase ac 10

r 0.5

%Elimite M 99

%Elimite N 1

%S 98

pH Log D" Cu Log D" Mn Log D" L im ite M" Log D" l im i te N"

0.00 -8.319 -19.379 2.30 -1.69

0.10 -7.919 -18.979 2.30 -1.69

0.20 -7.519 -18.579 2.30 -1.69 0.30 -7.119 -18.179 2.30 -1.69

0.40 -6.720 -17.780 2.30 -1.69

0.50 -6.320 -17.380 2.30 -1.69

0.60 -5.921 -16.981 2.30 -1.69

0.70 -5.521 -16.581 2.30 -1.69

0.80 -5.122 -16.182 2.30 -1.69

0.90 -4.724 -15.783 2.30 -1.69

1.00 -4.325 -15.385 2.30 -1.69

1.10 -3.927 -14.987 2.30 -1.69 1.20 -3.530 -14.589 2.30 -1.69

1.30 -3.133 -14.192 2.30 -1.69

1.40 -2.737 -13.795 2.30 -1.69

1.50 -2.342 -13.400 2.30 -1.69

1.60 -1.949 -13.005 2.30 -1.69

1.70 -1.558 -12.612 2.30 -1.69

1.80 -1.169 -12.221 2.30 -1.69

1.90 -0.785 -11.832 2.30 -1.69

2.00 -0.405 -11.445 2.30 -1.69

2.10 -0.032 -11.062 2.30 -1.69

2.20 0.331 -10.682 2.30 -1.69

2 30 0 683 10 308 2 30 1 69


32/38

4.30 3.335 -4.643 2.30 -1.69

4.40 3.345 -4.433 2.30 -1.69

4.50 3.352 -4.225 2.30 -1.69

4.60 3.358 -4.018 2.30 -1.69

4.70 3.362 -3.813 2.30 -1.69

4.80 3.366 -3.609 2.30 -1.69

4.90 3.369 -3.405 2.30 -1.69

5.00 3.371 -3.203 2.30 -1.69

5.10 3.373 -3.001 2.30 -1.69

5.20 3.374 -2.800 2.30 -1.69

5.30 3.376 -2.599 2.30 -1.69

5.40 3.377 -2.399 2.30 -1.69 5.50 3.377 -2.199 2.30 -1.69

5.60 3.378 -1.999 2.30 -1.69

5.70 3.378 -1.800 2.30 -1.69

5.80 3.379 -1.601 2.30 -1.69

5.90 3.379 -1.403 2.30 -1.69

6.00 3.379 -1.205 2.30 -1.69

6.10 3.379 -1.009 2.30 -1.69

6.20 3.379 -0.813 2.30 -1.69

6.30 3.380 -0.618 2.30 -1.69 6.40 3.380 -0.424 2.30 -1.69

6.50 3.380 -0.232 2.30 -1.69

6.60 3.380 -0.043 2.30 -1.69

6.70 3.380 0.145 2.30 -1.69

6.80 3.380 0.329 2.30 -1.69

6.90 3.380 0.511 2.30 -1.69

7.00 3.380 0.688 2.30 -1.69

7.10 3.380 0.860 2.30 -1.69

7.20 3.380 1.027 2.30 -1.69

7.30 3.380 1.188 2.30 -1.69

7.40 3.380 1.343 2.30 -1.69

7 50 3 380 1 490 2 30 1 69


33/38

9.50 3.380 2.777 2.30 -1.69

9.60 3.380 2.786 2.30 -1.69

9.70 3.380 2.793 2.30 -1.69

9.80 3.380 2.798 2.30 -1.69

9.90 3.380 2.802 2.30 -1.69

10.00 3.380 2.806 2.30 -1.69

10.10 3.380 2.809 2.30 -1.69

10.20 3.380 2.811 2.30 -1.69

10.30 3.380 2.813 2.30 -1.69

10.40 3.380 2.814 2.30 -1.69

10.50 3.380 2.815 2.30 -1.69

10.60 3.380 2.816 2.30 -1.69 10.70 3.380 2.817 2.30 -1.69

10.80 3.380 2.817 2.30 -1.69

10.90 3.380 2.818 2.30 -1.69

11.00 3.380 2.818 2.30 -1.69

11.10 3.380 2.819 2.30 -1.69

11.20 3.380 2.819 2.30 -1.69

11.30 3.380 2.819 2.30 -1.69

11.40 3.380 2.819 2.30 -1.69

11.50 3.380 2.819 2.30 -1.69 11.60 3.380 2.819 2.30 -1.69

11.70 3.380 2.819 2.30 -1.69

11.80 3.380 2.819 2.30 -1.69

11.90 3.380 2.819 2.30 -1.69

12.00 3.380 2.820 2.30 -1.69

12.10 3.380 2.820 2.30 -1.69

12.20 3.380 2.820 2.30 -1.69

12.30 3.380 2.820 2.30 -1.69

12.40 3.380 2.820 2.30 -1.69

12.50 3.380 2.820 2.30 -1.69

12.60 3.380 2.820 2.30 -1.69

12 70 3 380 2 820 2 30 1 69


34/38

pH %E Cu (II)" %E Mn(II)"

0.00 0.00 0.00

0.10 0.00 0.00

0.20 0.00 0.00 0.30 0.00 0.00

0.40 0.00 0.00

0.50 0.00 0.00

0.60 0.00 0.00

0.70 0.00 0.00

0.80 0.00 0.00

0.90 0.00 0.00

1.00 0.00 0.00

1.10 0.01 0.00 1.20 0.01 0.00

1.30 0.04 0.00

1.40 0.09 0.00

1.50 0.23 0.00

1.60 0.56 0.00

1.70 1.37 0.00

1.80 3.28 0.00

1.90 7.59 0.00

2.00 16.44 0.00

2.10 31.70 0.00

2.20 51.73 0.00

2 30 70 65 0 00


35/38

4.30 99.91 0.00

4.40 99.91 0.00

4.50 99.91 0.00

4.60 99.91 0.00

4.70 99.91 0.01

4.80 99.91 0.01

4.90 99.91 0.02

5.00 99.91 0.03

5.10 99.92 0.05

5.20 99.92 0.08

5.30 99.92 0.13

5.40 99.92 0.20 5.50 99.92 0.32

5.60 99.92 0.50

5.70 99.92 0.79

5.80 99.92 1.24

5.90 99.92 1.94

6.00 99.92 3.02

6.10 99.92 4.67

6.20 99.92 7.15

6.30 99.92 10.76 6.40 99.92 15.84

6.50 99.92 22.64

6.60 99.92 31.19

6.70 99.92 41.10

6.80 99.92 51.63

6.90 99.92 61.83

7.00 99.92 70.90

7.10 99.92 78.37

7.20 99.92 84.19

7.30 99.92 88.52

7.40 99.92 91.67

7 50 99 92 93 92


36/38

9.50 99.92 99.67

9.60 99.92 99.67

9.70 99.92 99.68

9.80 99.92 99.68

9.90 99.92 99.69

10.00 99.92 99.69

10.10 99.92 99.69

10.20 99.92 99.69

10.30 99.92 99.69

10.40 99.92 99.69

10.50 99.92 99.69

10.60 99.92 99.70 10.70 99.92 99.70

10.80 99.92 99.70

10.90 99.92 99.70

11.00 99.92 99.70

11.10 99.92 99.70

11.20 99.92 99.70

11.30 99.92 99.70

11.40 99.92 99.70

11.50 99.92 99.70 11.60 99.92 99.70

11.70 99.92 99.70

11.80 99.92 99.70

11.90 99.92 99.70

12.00 99.92 99.70

12.10 99.92 99.70

12.20 99.92 99.70

12.30 99.92 99.70

12.40 99.92 99.70

12.50 99.92 99.70

12.60 99.92 99.70

12 70 99 92 99 70


37/38

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LogD"M

"

pH

Log D" Cu

Log D" Mn

Log D" Limite M"

Log D" limite N"

Grafica de Log D" de M" y N" organico en funcin pH


38/38

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80

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%E Cu (II)"

%E Mn(II)"

Grafica de % Extraccin (%E) en funcin del pH de M" y N" fase organica en funcin pH

extraccion cu y mn con oxina large

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